Origin of the Earth—Moon system     

E. M. Galimov  A. M. Krivtsov 《Journal of Earth System Science》2005,114(6):593-600

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Transformation of arsenic compounds in modern intertidal sediments of Iriomote Island, Japan   总被引：1，自引：0，他引：1  

Harue Masuda  Yoshito Yamatani  Mitsuru Okai   《Journal of Geochemical Exploration》2005,87(2):587-81

The arsenic accumulation process in intertidal sediments of Iriomote Island, Japan, is analyzed as a naturally balanced arsenic-fixation system. Major and minor element chemistry is analyzed by X-ray fluorescence photometry, mineralogy is investigated by X-ray diffractometry, and four arsenic compounds are characterized by hydrogen-generated atomic absorption photometry. It is found that arsenic is accumulated by iron hydroxides/oxides precipitated following the decomposition of humic acids in the shallower sediment, and is subsequently incorporated into iron sulfide minerals at depth. The arsenic is immobile during incorporation into arsenic-bearing phases, suggesting that arsenic is unlikely to be released into the porewater under natural conditions in early diagenesis. The formation and decomposition of arsenic-bearing organic compounds appear to be associated with the formation and decomposition of arsenic in oxyhydroxides/oxides, suggesting that microbial activity may play an important role in controlling the behavior of arsenic and arsenic-bearing phases in the sediment column.  相似文献   

Effect of vegetation with different evolution degree on soil organic matter in a semi-arid environment (Cabo de Gata-Níjar Natural Park, SE Spain)     

V. Aranda  C. Oyonarte 《Journal of Arid Environments》2005,62(4):631-647

The organic matter of the surface horizons of soils developed below scrub vegetation in a Mediterranean semi-arid area of great environmental interest (Cabo de Gata-Níjar Natural Park, SE Spain) has been studied. The study mainly concentrates on examining the influence of two vegetation types, one evolved (according to its successional stage), and the other clearly degraded as a result of prior removal of vegetation. In spite of the homogeneity in the results obtained from the analysis of the organic matter from the soils studied, a relationship may be established between vegetation biotype and characteristics and evolution of the soil organic matter. The evolved vegetation results in the presence in the soil of a somewhat more evolved and stable organic matter (demonstrated by certain chemical and microbiological aspects), resulting in a greater degree of humification, thus favouring the protection of the soil and the ecosystem as a whole. Hence, the presence of degraded vegetation might lead to soil degradation, something that is unsustainable in semi-arid areas that are particularly fragile in nature.  相似文献   

矿物流体包裹体中的羧酸     

曾贻善  刘家齐 《矿物岩石地球化学通报》1997,(1)

矿物流体包裹体中的羧酸曾贻善刘家齐（北京大学地质系，北京１００８７１）（地矿部宜昌地质矿产研究所，宜昌４４３００３）关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团（—ＣＯＯＨ）的物质称为羧酸。Ｆｅｉｎ［１］和Ｓｈｏｃｋ［２］曾概述羧酸在自...  相似文献   

水资源中氯代烃污染物的去除方法   总被引：3，自引：0，他引：3  

李琳  刘菲 《黄金地质》2002,8(2):74-76

随着工业化的发展。氯代有机溶剂使用越来越广泛。并且难于去除。在20世纪90年代初期，人们就已认识到用Fe^0恢复污染的地下水的潜力。国外正在研究帮使用扔几种还原挥发性氯代烃的还原反应介质，尤其要提高的是双金属反应系统，反应速度快，而且脱Cl中国难解产物少，目前国也只停留在实验室研究阶段，个别做了地上反应器的验证实验，它的脱Cl机理、介质钝化和完全脱Cl问题还有待于进一步研究。  相似文献   

Amino acid nitrogen in atmospheric aerosols: Occurrence,sources and photochemical modification   总被引：2，自引：0，他引：2  

Peter J. Milne  Rod G. Zika 《Journal of Atmospheric Chemistry》1993,16(4):361-398

The presence of amino acids in atmospheric precipitation and aerosols has been noted for many years, yet relatively little is known about these or other nitrogen containing organic compounds in the atmosphere. Marine and continental rainwater analyses indicate that atmospheric aerosols, and subsequently atmospheric precipitation, may contain substantial levels of free and combined amino acids. The most likely source of amino N in the remote marine atmosphere appears to be the injection of proteinaceous material through the action of bursting bubbles at the sea-air interface or the long range transport from terrestrial sources. The capacity of these substrates to undergo photooxidation and photodegradation in the atmosphere to simpler species, such as ammonium ions, carboxylic acids, and for the S containing amino acids, oxidized forms of sulfur, has received little attention from atmospheric chemists. The photochemistry of covalently bound amino groups, particularly as found in peptides and amino acids, is discussed here with the purpose of summarizing what is known of their occurrence and their possible importance to atmospheric chemistry.  相似文献   

Characterization of two newArtemia populations from two solar saltworks of Lesbos Island (Greece): biometry,hatching characteristics and fatty acid profile   总被引：1，自引：0，他引：1  

G. V. Triantaphyllidis  T. J. Abatzopoulos  R. M. Sandaltzopoulos  G. Stamou  C. D. Kastritsis 《International Journal of Salt Lake Research》1993,2(1):59-68

Cysts of two parthenogeneticArtemia strains from the Kalloni and Polychnitos saltworks on Lesbos Island were evaluated for their potential use in aquaculture. The characterizations performed were: cyst and naupliar biometrics, cyst hatching characteristics, and fatty acid profile of instar-I nauplii. Deactivation of diapause after treatment with H₂O₂ and/or decapsulation were applied in order to improve cyst hatchability. The evaluation revealed that the strains studied exhibit acceptable hatching characteristics for parthenogeneticArtemia and that the fatty acid profile of the Kalloni strain is excellent for use in culturing marine fishes and crustaceans. Statistical analyses on cyst and naupliar biometrics showed that the two populations characterized are almost identical and very similar to other Greek parthenogenetic strains.  相似文献   

The Partitioning of Tungsten bwtween Aqueous Fluids and Silicate Melts     

Xu Yongsheng  Zhang Benren  Han Yinwen 《中国地球化学学报》1993,12(2):128-136

An experimental study has been carried out to determine the partition coefficients of tungsten between aqueous fluids and granitic melts at 800 °C and 1.5 kb with natural granite as the starting material. The effects of the solutions on the partition coefficients of tungsten show a sequence of P > CO ₃ ²⁻ > B > H₂O. The effects are limited (generallyK _D < 0.3) and the tungsten shows a preferential trend toward the melt over the aqueous fluid. The value ofK _D increases with increasing concentration of phosphorus; theK _D increases first and then reduces with the concentration of CO ₃ ²⁻ when temperature decreases, theK _D between the solution of CO ₃ ²⁻ and the silicate melt increases, and that between the solution of B₄O ₇ ²⁻ and the silicate melt decreases. The partition coefficients of phosphorus and sodium between fluids and silicate melts have been calculated from the concentrations of the elements in the melts. TheK _D value for phosphorus is 0.38 and that for sodium is 0.56. Evidence shows that the elements tend to become richer and richer in the melts.  相似文献   

Characterisation of brown coal humic acids and modified humic acids using pyrolysis gcms and other techniques     

W. R. Jackson  G. D. Bongers  P. J. Redlich  G. Favas  Y. Fei  A. F. Patti  R. B. Johns 《International Journal of Coal Geology》1996,32(1-4)

It has been proposed that Victorian brown coal can be considered as a two-component structure — a lignocellulosic “host”, containing various amounts of weakly bound or entrapped “guest” material together with very small amounts of inorganic and/or mineral matter. The latter predominantly consists of wax esters and/or terpenoid material. In this paper we describe attempts to gain structural information regarding the more complex, “host” component of the coal. Our initial model compound has been humic acid that can be readily obtained from the coal by alkaline extraction. It has been found that “pure” humic acid, free from material associated with the “guest” components of the coal, can be obtained by a highly selective, low-yielding alkaline extraction. This humic acid has been studied by nmr spectroscopy and pyrolysis gas chromatography-mass spectroscopy (py-gc/ms). The products arising from py-gc/ms have been compared with those obtained from similar pyrolysis of whole coals. Alkylation of humic acids using alkyl halides in the presence of base has been successfully carried out and reactivity of the resulting materials compared with those of the parent coal and humic acid.  相似文献   

沉积盆地流体—岩石相互作用研究的现状   总被引：17，自引：0，他引：17  

蔡春芳 《地球科学进展》1996,11(6):575-579

沉积盆地流体－岩石相互作用研究主要是通过实验地球化学和岩石学，地球化学模拟方法开展的，综述了这一领域的研究现状，主要包括有机酸来源和分布及期 对矿物稳定性的影响，地层水成因与演化、烃类与岩石间的氧化还原反应、以及储层润湿性的变化等，并展望了其 发展趋势。  相似文献